Behavior of the Enthalpy of Adsorption in Nanoporous Materials Close to Saturation Conditions

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Behavior of the Enthalpy of Adsorption in Nanoporous Materials Close to Saturation Conditions

Many important industrial separation processes based on adsorption operate close to saturation. In this regime, the underlying adsorption processes are mostly driven by entropic forces. At equilibrium, the entropy of adsorption is closely related to the enthalpy of adsorption. Thus, studying the behavior of the enthalpy of adsorption as a function of loading is fundamental to understanding sepa...

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ژورنال

عنوان ژورنال: Journal of Chemical Theory and Computation

سال: 2017

ISSN: 1549-9618,1549-9626

DOI: 10.1021/acs.jctc.6b01193